Wide-angle x-ray diffraction evidence of structural coherence in CsPbBr₃ nanocrystal superlattices

Summary, in English

Films made of colloidal CsPbBr₃ nanocrystals packed in isolated or densely-packed superlattices display a remarkably high degree of structural coherence. The structural coherence is revealed by the presence of satellite peaks accompanying Bragg reflections in wide-angle X-ray diffraction experiments in parallel-beam reflection geometry. The satellite peaks, also called “superlattice reflections”, arise from the interference of X-rays diffracted by the atomic planes of the orthorhombic perovskite lattice. The interference is due to the precise spatial periodicity of the nanocrystals separated by organic ligands in the superlattice. The presence of satellite peaks is a fingerprint of the high crystallinity and long-range order of nanocrystals, comparable to those of multilayer superlattices prepared by physical methods. The angular separation between satellite peaks is highly sensitive to changes in the superlattice periodicity. These characteristics of the satellite peaks are exploited to track the superlattice compression under vacuum, as well as to observe the superlattice growth in situ from colloidal solutions by slow solvent evaporation.

• Author: Stefano Toso; Dmitry Baranov; Cinzia Giannini; Sergio Marras; Liberato Manna
• Publishing year: 2019
• Language: English
• Pages: 272-276
• Publication/Series: ACS Materials Letters
• Volume: 1
• Issue: 2
• Links: http://dx.doi.org/10.1021/acsmaterialslett.9b00217
• Document type: Journal article
• Publisher: The American Chemical Society (ACS)
• Status: Published
• ISBN/ISSN/Other: ISSN: 2639-4979