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Ebbe Nordlander. Portrait.

Ebbe Nordlander

Professor

Ebbe Nordlander. Portrait.

Diastereomeric control of enantioselectivity: evidence for metal cluster catalysis.

Author

  • Ahmed Abdel-Magied
  • Amrendra Singh
  • Matti Haukka
  • Michael G Richmond
  • Ebbe Nordlander

Summary, in English

Enantioselective hydrogenation of tiglic acid effected by diastereomers of the general formula [(μ-H)2Ru3(μ3-S)(CO)7(μ-P-P*)] (P-P* = chiral Walphos diphosphine ligand) strongly supports catalysis by intact Ru3 clusters. A catalytic mechanism involving Ru3 clusters has been established by DFT calculations.

Department/s

  • Chemical Physics

Publishing year

2014

Language

English

Pages

7705-7708

Publication/Series

Chemical Communications

Volume

50

Issue

57

Document type

Journal article

Publisher

Royal Society of Chemistry

Topic

  • Chemical Sciences

Status

Published

ISBN/ISSN/Other

  • ISSN: 1364-548X