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Ebbe Nordlander. Portrait.

Ebbe Nordlander

Professor

Ebbe Nordlander. Portrait.

Hexakis(tetraaquasodium) decavanadate(V) dihydrate

Author

  • Jessica Nilsson
  • Ebbe Nordlander
  • Ulrich Behrens
  • Dieter Rehder

Summary, in English

The title compound, {[Na(H2O)(4)](6)[V10O28]center dot 2H(2)O}n, crystallized from a H2O/THF/CH3CN solution (pH ca 6)containing equimolar amounts of NaVO3 and N-(2-hydroxybenzyl)-N-(2-picolyl) glycine. In the crystal structure, the decavanadate [V10O28](6-) anion ((1) over bar symmetry)is coordinated, via four terminal oxide ligands of V centres, to two dinuclear [{Na(H2O)(3)}(2)(mu-H2O)(2)](2+) units. Interconnection of these aquasodium-ion-sandwiched decavanadates to chains parallel to [001]is effected by mu-[{Na(H2O)(3)}(2)(mu-H2O)(2)](2+) units, bridging adjacent decavanadates via O=V. The structure is consolidated by an extensive network of O-H center dot center dot center dot O hydrogen bonds.

Department/s

  • Chemical Physics

Publishing year

2010

Language

English

Pages

30-148

Publication/Series

Acta Crystallographica Section E: Structure Reports Online

Volume

66

Document type

Journal article

Publisher

International Union of Crystallography

Topic

  • Atom and Molecular Physics and Optics

Status

Published

ISBN/ISSN/Other

  • ISSN: 1600-5368