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Ebbe Nordlander. Portrait.

Ebbe Nordlander

Professor

Ebbe Nordlander. Portrait.

The redox interaction between the vanadyl cation and tris[6-(2-hydroxymethyl)pyridylmethyl]amine

Author

  • Jessica Nilsson
  • Stephen B. Colbran
  • Ulrich Behrens
  • Dieter Rehder
  • Ebbe Nordlander

Summary, in English

Reaction of tris[6-(2-hydroxymethyl)pyridylmethyl]amine, tpa(OH)(3), with (VOSO4)-O-IV center dot 5H(2)O resulted in an unexpected redox reaction producing [(VLH)-L-III][(VLH2)-L-III][PF6](3)center dot 1.5H(2)O (where H3L is bis(2-hydroxymethylpyridyl)(2-carboxypyridylmethyl)amine). This reaction is interesting in the light of the ability of ascidians to accumulate V-III by reduction of V-V from sea water. It also provides additional proof to the susceptibility of pyridylmethylamines to oxidation by certain metal ions. (C) 2012 Elsevier B. V. All rights reserved.

Department/s

  • Chemical Physics

Publishing year

2012

Language

English

Pages

490-493

Publication/Series

Inorganica Chimica Acta

Volume

392

Document type

Journal article

Publisher

Elsevier

Topic

  • Atom and Molecular Physics and Optics

Keywords

  • Vanadium
  • Vanadyl cation
  • Reduction
  • Ascidians

Status

Published

ISBN/ISSN/Other

  • ISSN: 0020-1693