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Ebbe Nordlander. Portrait.

Ebbe Nordlander

Professor

Ebbe Nordlander. Portrait.

Detection of a Novel Intermediate in the Addition of Thiols to Osmium Carbonyl Clusters

Author

  • Lars Ivar Elding
  • Ebbe Nordlander
  • Keranio Kiriakidou
  • Maria R. Plutino
  • Fabio Prestopino
  • Magda Monari
  • Maria Johansson
  • Esteve Valls
  • Roberto Gobetto
  • Silvio Aime

Summary, in English

Spectroscopic studies of the reaction of [Os-3(CO)(11)MeCN)] with para-thiocresol to form [Os-3(mu-H)(CO)(10)(mu-SC6H4Me-p)] indicate that the reaction proceeds via a two-step consecutive process involving the intermediate [Os-3(CO)(11)-(MeC6H4SH-p)], in which there is an agostic Os-H-S interaction.

Department/s

  • Centre for Analysis and Synthesis
  • Chemical Physics

Publishing year

1998

Language

English

Pages

2721-2722

Publication/Series

Chemical Communications

Volume

1998

Issue

24

Document type

Journal article

Publisher

Royal Society of Chemistry

Topic

  • Inorganic Chemistry

Keywords

  • Osmium carbonyls
  • Cluster complex
  • Addition Reactions
  • Kinetics
  • Reaction mechanism

Status

Published

ISBN/ISSN/Other

  • ISSN: 1364-548X