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Ebbe Nordlander. Portrait.

Ebbe Nordlander

Professor

Ebbe Nordlander. Portrait.

Solution and structural studies of the Cd(II) - Aconitate system

Author

  • George Kostakis
  • Gerasimos Malandrinos
  • Ebbe Nordlander
  • Matti Haukka
  • John C. Plakatouras

Summary, in English

The complexing ability of the binary system trans-aconitic acid (H3L) with regard to Cd(II) and the crystal structures of the binary system Cd(II)-(H3L), [Cd3L2(H2O)(6)] n(1) and ternary systems of Cd(II)-(H3L)-Lewis base [Lewis base = 1,10-phenanthroline (2) and 2,2'-bipyridine (3)] have been determined. Compound I is a rare binodal four-connected three-dimensional (3D) metal-organic framework possessing a moganite (mog) topology. Compounds 2 and 3 represent infinite one-dimensional (1D) chains forming three-dimensional metal-supramolecular structures through H-bond and pi-pi stacking interactions. All compounds have been characterized by spectroscopic and thermogravimetric techniques. (C) 2009 Elsevier Ltd. All rights reserved.

Department/s

  • Chemical Physics

Publishing year

2009

Language

English

Pages

3227-3234

Publication/Series

Polyhedron

Volume

28

Issue

15

Document type

Journal article

Publisher

Elsevier

Topic

  • Atom and Molecular Physics and Optics

Keywords

  • Topology
  • Coordination polymers
  • Lewis base
  • Potentiometry
  • Cadmium complexes

Status

Published

ISBN/ISSN/Other

  • ISSN: 0277-5387