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Ebbe Nordlander. Portrait.

Ebbe Nordlander

Professor

Ebbe Nordlander. Portrait.

Luminescent PhotoCORMs : Enabling/Disabling CO Delivery upon Blue Light Irradiation

Author

  • Vitor C. Weiss
  • Giliandro Farias
  • André L. Amorim
  • Fernando R. Xavier
  • Tiago P. Camargo
  • Mayana B. Bregalda
  • Matti Haukka
  • Ebbe Nordlander
  • Bernardo De Souza
  • Rosely A. Peralta

Summary, in English

The new luminescent carbonyl compounds [Mn(Oxa-H)(CO)3Br] (1) and [Mn(Oxa-NMe2)(CO)3Br] (2) were synthesized and fully characterized. Complexes 1 and 2 showed CO release under blue light (λ453). Spectroscopic techniques and TD-DFT and SOC-TD-DFT calculations indicated that 1 and 2 release the Oxa-H and Oxa-NMe2 coligands in addition to the carbonyl ligands, increasing the luminescence during photoinduction.

Department/s

  • Chemical Physics

Publishing year

2020

Language

English

Pages

13078-13090

Publication/Series

Inorganic Chemistry

Volume

59

Issue

18

Document type

Journal article

Publisher

The American Chemical Society (ACS)

Topic

  • Inorganic Chemistry

Status

Published

ISBN/ISSN/Other

  • ISSN: 0020-1669