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Ebbe Nordlander. Portrait.

Ebbe Nordlander

Professor

Ebbe Nordlander. Portrait.

Evidence that steric factors modulate reactivity of tautomeric iron-oxo species in stereospecific alkane C-H hydroxylation.

Author

  • Mainak Mitra
  • Julio Lloret-Fillol
  • Matti Haukka
  • Miquel Costas
  • Ebbe Nordlander

Summary, in English

A new iron complex mediates stereospecific hydroxylation of alkyl C-H bonds with hydrogen peroxide, exhibiting excellent efficiency. Isotope labelling studies provide evidence that the relative reactivity of tautomerically related oxo-iron species responsible for the C-H hydroxylation reaction is dominated by steric factors.

Department/s

  • Chemical Physics

Publishing year

2014

Language

English

Pages

1408-1410

Publication/Series

Chemical Communications

Volume

50

Issue

12

Document type

Journal article

Publisher

Royal Society of Chemistry

Topic

  • Chemical Sciences

Status

Published

ISBN/ISSN/Other

  • ISSN: 1364-548X