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Ivan Scheblykin. Portrait.

Ivan Scheblykin

Professor

Ivan Scheblykin. Portrait.

Metal-exchange reaction between cadmium tetraphenylporphyrinates and copper(II) in dimethylformamide

Author

  • S. V. Zvezdina
  • O. V. Mal'tseva
  • N. V. Chizhova
  • Ivan Scheblykin
  • N. Zh. Mamardashvili

Summary, in English

The metal-exchange reaction of cadmium 5,10,15,20-tetraphenylporphyrinate (CdTPP) and cadmium 2-bromo-5,10,15,20-tetraphenylporphyrinate (CdTPPBr) with copper acetate (Cu(OAc)(2)) in dimethylformamide was studied spectrophotometrically. The kinetic parameters of the metal-exchange reaction were determined. A possible stoichiometric reaction mechanism was proposed.

Department/s

  • Chemical Physics

Publishing year

2013

Language

English

Pages

486-490

Publication/Series

Russian Journal of Inorganic Chemistry

Volume

58

Issue

4

Document type

Journal article

Publisher

Pleiades Publishing

Topic

  • Atom and Molecular Physics and Optics

Status

Published

ISBN/ISSN/Other

  • ISSN: 0036-0236